Synthesis, structural characterization and reactivity towards methanol of a bis(silyl)platinum(II) complex bearing a chelating depe ligand
| Autor: | Yong-Hua Li, Shi Wang, Wenjin Zeng, Chao Huang, Guo Jinfei, Jia-Yi Zhu, Shuang-Shuang Sun, Wei Huang |
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| Rok vydání: | 2016 |
| Předmět: |
Steric effects
Silylation 010405 organic chemistry Stereochemistry Ligand chemistry.chemical_element 010402 general chemistry 01 natural sciences Medicinal chemistry 0104 chemical sciences Inorganic Chemistry chemistry.chemical_compound chemistry Materials Chemistry Reactivity (chemistry) Chelation Methanol Physical and Theoretical Chemistry Platinum Single crystal |
| Zdroj: | Inorganica Chimica Acta. 446:93-96 |
| ISSN: | 0020-1693 |
| DOI: | 10.1016/j.ica.2016.02.051 |
| Popis: | Treatment of 1,2-C6H4(SiH3)(SiH3) (1) with [Pt(depe)(PEt3)2] (depe = Et2PCH2CH2PEt2) in the ratio of 1:1 yields the complex [PtII{1,2-C6H4(SiH2)(SiH2)}(depe)] (2), which has unique reactivity towards sterically unhindered alcohol to form an unusual tetra-alkoxy substituted silyl platinum(II) compound (3). Only 2 examples of bis(silyl)platinum(II) complexes prepared from this chelating hydrosilane ligand have been registered in the Cambridge Structural Database. The structure of complex (3) was unambiguously determined by multinuclear NMR spectroscopic studies and single crystal X-ray analysis. |
| Databáze: | OpenAIRE |
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