The MnPS3 layered phase as a substrate for aggregate formation: the example of triarylpyrylium cations

Autor:	René Clément, Michèle Veber, Thibaud Coradin, Anthony H. Francis
Rok vydání:	1998
Předmět:	Absorption spectroscopy Chemical physics Chemistry Phase (matter) Intercalation (chemistry) X-ray crystallography Materials Chemistry Organic chemistry General Chemistry Dielectric Crystal structure Absorption (chemistry) Powder diffraction
Zdroj:	Journal of Materials Chemistry. 8:1471-1475
ISSN:	1364-5501 0959-9428
DOI:	10.1039/a801068d
Popis:	Intercalation of triarylpyrylium salts into the MnPS3 layered phase has been achieved. The formation of J-aggregates in the interlayer space is suggested on the basis of UV–VIS absorption and emission spectroscopy experiments. The extended dipole model approximation is used to derive structural information that appears consistent with the X-ray powder diffraction data. However, in contrast to previous results, none of the intercalates exhibit any second harmonic generation. Finally, the important influence of the host phase dielectric properties on aggregate formation is emphasized.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7aab0c4dd251e0e2f6a04237e37c20ab https://doi.org/10.1039/a801068d Zobrazit plný text záznamu