Ferrocene polymers. synthesis and polymerization of p-ferocenecenylphenylacetylene
| Autor: | Cristofor Simionescu, Tatiana Lixandru, L. Tataru, I. Mazilu |
|---|---|
| Rok vydání: | 1976 |
| Předmět: |
chemistry.chemical_classification
Radical Organic Chemistry Polymer Photochemistry Biochemistry Inorganic Chemistry chemistry.chemical_compound Residue (chemistry) Monomer chemistry Phenylacetylene Ferrocene Polymerization Polymer chemistry Materials Chemistry Thermal stability Physical and Theoretical Chemistry |
| Zdroj: | Journal of Organometallic Chemistry. 113:23-28 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/s0022-328x(00)91757-1 |
| Popis: | To investigate the influence of the ferrocenyl residue on the reactivity of phenylacetylene towards polymerization and on the properties of polyphenylacetylene, p-ferrocenylphenylacetylene has been synthesised and then polymerized with initiation by free radicals. Theoretical studies on the reactivity of p-ferrocenylphenylacetylene showed good agreement with the observation that the reactivity of this monomer is lower when compared to that of ferrocenylacetylene. The polymers synthesised showed good thermal stability |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|