Dehydrogenative Formation of a (η4-Enone)ruthenium(0) Complex as a Key Intermediate in the Catalytic Isomerization of Allylic Alcohol to Ketone

Autor:	Yuya Imai, Sanshiro Komiya, Nobuyuki Komine, Susumu Kanaya, Masafumi Hirano
Rok vydání:	2005
Předmět:	chemistry.chemical_classification Allylic rearrangement Ketone Organic Chemistry chemistry.chemical_element Allylic alcohol Medicinal chemistry Ruthenium Catalysis Inorganic Chemistry chemistry.chemical_compound chemistry Organic chemistry Physical and Theoretical Chemistry Enone Isomerization
Zdroj:	Organometallics. 24:1059-1061
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om0489711
Popis:	(η4-Enone)ruthenium(0) complexes, Ru[η4-CH2CHC(R)O](PEt3)3 (R = H (3), Me (4)), are prepared by the reactions of Ru(η4-1,5-COD)(η6-1,3,5-COT) (1)/PEt3 and Ru(η4-1,3,5-COT)(PEt3)3 (2) with allylic a...
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7a928cda1c2db948649e31659ba52386 https://doi.org/10.1021/om0489711 Zobrazit plný text záznamu