ChemInform Abstract: Novel Acylation of a Vinyl Group by the Reaction of an Aldehyde and a Vinylselenonium Ylide

Autor:	Tomokazu Kusumoto, Chikayo Yoshida, Shin-ichi Watanabe, Tadashi Kataoka
Rok vydání:	2010
Předmět:	chemistry.chemical_classification Acylation chemistry.chemical_compound chemistry Base (chemistry) Ylide Potassium hydride Sodium Salt (chemistry) chemistry.chemical_element General Medicine Aldehyde Medicinal chemistry
Zdroj:	ChemInform. 32
ISSN:	1522-2667 0931-7597
Popis:	Vinylselenonium ylide, which was generated from (Z)-vinylselenonium salt with a base such as sodium or potassium hydride, reacted with aromatic aldehydes to produce the α,β-unsaturated ketones, which were obtained in better yields from the aldehydes with an electron-withdrawing group than from those with an electron-donating group.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7a91ebbc22db955c1985207cfb265ccf https://doi.org/10.1002/chin.200135099 Zobrazit plný text záznamu Plný text