Spectroscopic study of rotational isomerism in triethylarsine sulfide

Autor:	D. F. Fazliev, R. R. Shagidullin, S. V. Izosimova
Rok vydání:	1978
Předmět:	chemistry.chemical_classification Sulfide Solid-state Infrared spectroscopy General Chemistry Symmetry (physics) symbols.namesake chemistry Normal mode symbols Physical chemistry Molecule Organic chemistry Raman spectroscopy Conformational isomerism
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 27:302-305
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00923864
Popis:	1. A study has been made of the Raman and IR spectra of triethylarsine sulfide (TEAS), in the solid and liquid states, in various solvents, and at various temperatures. 2. In the solid state, TEAS appears as an isomer with C3 symmetry, the three C2H3 groups being gauche-oriented with respect to the As=S bond. In the molten form, and in solutions, the compound appears as an equilibrium mixture of three isomers with C2, Cs, and C3 symmetries. 3. Frequencies and normal vibration modes have been calculated for these three conformers of the TEAS molecule.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7a8e858202e6bfddf580acfade526c62 https://doi.org/10.1007/bf00923864 Zobrazit plný text záznamu Full text from SpringerLink