Optical activity, solvation state, and conformations ofL-?-alanine in water-organic solvents

Autor:	F. V. Devyatov, S. G. Abdullina, Yu. I. Sal'nikov, I. A. Nuretdinov, S. G. Vul'fson, A. R. Mustafina, Valentina P. Gubskaya
Rok vydání:	1993
Předmět:	Alanine Circular dichroism Chemistry Computational chemistry Organic solvent Solvation Molecule Organic chemistry sense organs General Chemistry Solubility equilibrium L-α-alanine Equilibrium constant
Zdroj:	Russian Chemical Bulletin. 42:1007-1009
ISSN:	1573-9171 1066-5285
DOI:	10.1007/bf00704186
Popis:	The solvation effect on the conformational equilibrium ofL-α-alanine in binary water-organic solvents (H2O-acetonitrile, H2O-DMF) was studied. This manifests itself in changes in the optical activity and CD intensity. Equilibrium constants for the substitution of water molecules by organic solvent molecules were determined.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7a82bcdaf1dbd214d1acf1a46ff970b0 https://doi.org/10.1007/bf00704186 Zobrazit plný text záznamu Full text from SpringerLink