A novel Nb and Cu co-doped SrCoO3-δ cathode for intermediate temperature solid oxide fuel cells
| Autor: | Shiru Le, Xueqin Song, Xiao-Dong Zhu, Naiqing Zhang, Yujie Feng, Yanxiang Zhang, Zaifang Yuan, Chunfeng Li, Yachun Mao |
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| Rok vydání: | 2020 |
| Předmět: |
Cerium oxide
Order of reaction Materials science Renewable Energy Sustainability and the Environment Doping Oxide Energy Engineering and Power Technology 02 engineering and technology Activation energy Electrolyte 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences Cathode 0104 chemical sciences law.invention chemistry.chemical_compound Fuel Technology chemistry Chemical engineering law 0210 nano-technology Polarization (electrochemistry) |
| Zdroj: | International Journal of Hydrogen Energy. 45:10862-10870 |
| ISSN: | 0360-3199 |
| Popis: | The extensive explorations of potential cathode materials are prominently critical for the rapid development of high performance solid oxide fuel cells (SOFCs). Herein, we develop a novel Nb and Cu co-doped SrCoO3-δ (SCNC) cathode base on solid state reaction, which exhibits decent compatibility with gadolinium doped cerium oxide (GDC) electrolyte. The SCNC is successfully stabilized with cubic structure at room temperature when incorporating of small amount of high valence Nb5+. Meanwhile, the oxygen vacancy concentration of SCNC is efficiently improved with the addition of Cu. The Nb and Cu co-doping also substantially promotes the electronic conductivity, achieving 550 S cm−1 for the optical doped SrCo0.85Nb0.05Cu0.10O3-δ (SCNC10) at 400 °C. In addition, the polarization of SCNC is remarkably reduced, reaching as low as 0.021 Ω cm2 for SCNC10 at 700 °C. The activation energy for reaction is also significantly lowered to 0.78 eV. The reaction order m is deduced to be about 0.30, implying that the rate determination step for SCNC10 is the charge transfer reaction. The peak power density of the single cell reaches 780 mW cm−2 at 800 °C. All these outstanding performances demonstrate that SCNC is a promising cathode for SOFCs when operating at intermediate temperature (IT). |
| Databáze: | OpenAIRE |
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