Spectroscopic and acoustic study in binary mixtures of glycerol with several alkanols

Autor:	Necmettin Caner, Gokhan Savaroglu
Rok vydání:	2010
Předmět:	Isentropic process Hydrogen bond Intermolecular force Infrared spectroscopy Thermodynamics Condensed Matter Physics Electronic Optical and Magnetic Materials chemistry.chemical_compound chemistry Speed of sound otorhinolaryngologic diseases Materials Chemistry Glycerol Molecule Methanol Physical and Theoretical Chemistry
Zdroj:	Physics and Chemistry of Liquids. 48:108-116
ISSN:	1029-0451 0031-9104
DOI:	10.1080/00319100802716641
Popis:	Speeds of sound and densities of glycerol + methanol, glycerol + ethanol and glycerol + 2-propanol, were measured over the entire composition range at 298.15 K. The excess volumes, the isentropic compressibilities, molar isentropic compressibilities and excess molar isentropic compressibilities and excess speeds of sound were estimated from the densities and speeds of sound. The results indicated the presence of interactions between unlike molecules through intermolecular hydrogen bonding. The excess volumes, excess molar isentropic compressibilities and excess speeds of sound of the binary mixtures were fitted to the Redlich–Kister equation. The infrared spectra of glycerol + methanol, glycerol + ethanol and glycerol + 2-propanol have been recorded for various concentrations at room temperature. IR stretching frequencies, bandwidths and relative intensities have been estimated and analysed. Acoustic and spectroscopic measurements showed a good correlation to explain the existence of interactions between ...
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7a65e3850168b1c393d9589186df48ff https://doi.org/10.1080/00319100802716641 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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