Ferrocenium hexafluorophosphate: molecular dynamics in the solid state

Autor:	Michio Sorai, Richard J. Wittebort, Robert J. Webb, David N. Hendrickson, Michael D. Lowery, Yutaka Shiomi
Rok vydání:	1992
Předmět:	Stereochemistry Crystal structure Nuclear magnetic resonance spectroscopy Inorganic Chemistry chemistry.chemical_compound Crystallography chemistry X-ray crystallography Proton NMR Molecule Physical and Theoretical Chemistry Metallocene Single crystal Monoclinic crystal system
Zdroj:	Inorganic Chemistry. 31:5211-5219
ISSN:	1520-510X 0020-1669
DOI:	10.1021/ic00051a011
Popis:	The nature of the molecular dynamo associated with the cation of ferrocenium hexafluorophosphate is probed with solid-state 2 H NMR, 57 Fe Mosbauer, and single-crystal X-ray diffraction techniques. At room temperature [Fe-(C 5 H 5 ) 2 ]PFa crystallizes in the monoclinic space group P2 1 /c which at 299 K has a=13.408 (6) A, b=9.530 (2) A, c=9.482 (2) A, β=93.17 (3) o , z=4, and d calc =1.818 g cm -3 . Least-squares refinement with 1429 observed reflections led to R=0.067 and R w =0.085
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7a5c80e929004cb2af3de9e2a5cda9e4 https://doi.org/10.1021/ic00051a011 Zobrazit plný text záznamu