Core–shell nanostructure electrodes for improved electrocatalytic properties in methanol electrooxidation

Autor:	Young-Woo Lee, Seong-Bae Kim, Kyung-Won Park, Inchul Hwang, Jongmin Lee, Bumwook Roh, Do-Young Kim, Sang-Beom Han
Rok vydání:	2012
Předmět:	Materials science Nanostructure Process Chemistry and Technology Inorganic chemistry Shell (structure) chemistry.chemical_element Core (manufacturing) Catalysis chemistry.chemical_compound chemistry Electrode Methanol Tin Carbon General Environmental Science
Zdroj:	Applied Catalysis B: Environmental. :200-207
ISSN:	0926-3373
Popis:	TiN@C nanostructure supports consist of TiN as a core prepared at 900 °C in NH 3 and carbon as a shell by heat treatment of the TiN at 900 °C in CH 4 for 1, 3, and 6 h (referred as TiN@C-1 h, TiN@C-3 h, and TiN@C-6 h). The thickness of the carbon shell layers in the TiN@C supports increase with increasing reaction time at 900 °C in CH 4 . In particular, the TiN@C-1 h supported Pt catalyst exhibits much improved electrocatalytic properties toward methanol electrooxidation as compared to Pt catalysts on Vulcan XC-72R.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7a4d0a53e1e9e1d2a86019b7ed42e58c https://doi.org/10.1016/j.apcatb.2011.09.036 Zobrazit plný text záznamu Full Text from ScienceDirect