An iron-based micropore-enriched silica catalyst: in situ confining of Fe2O3 in the mesopores and its improved catalytic properties
| Autor: | Yan Kong, Saifu Long, Tao Xi, Shijian Zhou, Kangchao Lu, Fu Yang |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
General Chemical Engineering
Catalyst support Inorganic chemistry 02 engineering and technology General Chemistry Microporous material Mesoporous silica 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Catalysis Hydroxylation chemistry.chemical_compound chemistry Chemical engineering Phenol 0210 nano-technology Selectivity Mesoporous material |
| Zdroj: | RSC Advances. 6:76064-76074 |
| ISSN: | 2046-2069 |
| Popis: | Surface exposed catalytic active species are thought to be responsible for overall catalytic activity and selectivity. In this paper, controllable contents of iron oxides were in situ introduced into the inner surface of anionic surfactant-templated mesoporous silica (AMS) by the metal-modified anionic surfactant templating route, in which anionic micelles decorated with different amounts of Fe2+ were direct utilized to assemble with organosilicate. The characterization results demonstrated that, after thermal treatments, Fe2O3 species were in situ formed and highly-dispersed in the channels of AMS, and the pore size was accordingly tailored to the microporous level ( |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|