| Popis: |
Isotropic naphthalene and hydrogenated coal tar pitches with a lower softening point were air blown at 330°C with or without addition of 1,8-dinitronaphthalene (DNN) in order to prepare a fully isotropic pitch with a higher softening point. The softening point of the naphthalene and hydrogenated coal tar pitches could be raised to approximately 240°C and 275°C, respectively, by air or nitrogen blowing with 5 to 15 wt% DNN, while the softening point of naphthalene pitch was only raised to 200~210°C by air blowing without DNN. To retain the isotropic texture of naphthalene pitch, the reaction conditions, including amounts of additive, blowing temperatures, soak times at the blowing temperature, as well as blowing atmospheres need to be controlled. Air blowing at the high temperature of 330°C promoted the dehydrogenation and aromatization through a significant reduction of aliphatic or naphthenic hydrogens. Thermal decomposition of DNN during blowing treatment created NO 2 or NO which may initiate oxidation or radical reactions, accelerating the condensation of naphthalene and hydrogenated coal tar pitches. |
