Autor: |
Susumu Harashima, Shigeo Amemiya, Koichi Kojima, Osamu Oda |
Rok vydání: |
1991 |
Předmět: |
|
Zdroj: |
Tetrahedron. 47:2773-2784 |
ISSN: |
0040-4020 |
Popis: |
A new reducing agent ( 2j ) reduced the enone ( 4 ) to give 15( S )-allylic alcohol ( 5a ) with excellent regio- and stereoselectivity through a five membered ring transition state. Stereoselecrivity of this reaction will be explained based on the LUMO of the enone moiety. The resulting ( 5a ) was led to a carbacyclin. |
Databáze: |
OpenAIRE |
Externí odkaz: |
|