N-Methylaniline-induced Si–Si bond cleavages of perchlorooligosilanes

Autor:	Sung Jin Park, Myong Euy Lee, Cheol Hyun Kim, Jong Min Choi, Hyeon Mo Cho
Rok vydání:	2014
Předmět:	Inorganic Chemistry chemistry.chemical_compound chemistry Organic Chemistry Materials Chemistry N-Methylaniline Disproportionation Amine gas treating Physical and Theoretical Chemistry Photochemistry Biochemistry Medicinal chemistry Bond cleavage
Zdroj:	Journal of Organometallic Chemistry. 768:140-144
ISSN:	0022-328X
DOI:	10.1016/j.jorganchem.2014.06.030
Popis:	This study describes Si–Si bond cleavage of perchlorooligosilane using an amine. N-Methylaniline-induced Si–Si bond cleavage reactions of cyclic perchlorosilanes Si5Cl10 (1) and Si4Cl8 (2), and acyclic perchlorosilanes Si5Cl12 (3) and Si2Cl6 (4) yielded the N,N-methylphenylamino-substituted monosilanes, (NMePh)3−nSiHCln (5; n = 2, 6; n = 1, 7; n = 0) and (NMePh)4-nSiCln (8; n = 2, 9; n = 3). Products and yields depended on the perchlorooligosilanes used. In addition, disproportionation between Si–N and Si–Cl bonds was observed in reactions of compounds 5 and 9.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::79d8010850d7f02008e396f085a006d2 https://doi.org/10.1016/j.jorganchem.2014.06.030 Zobrazit plný text záznamu Full Text from ScienceDirect