Conductance Matrix of Amphoteric Ion-Exchange Membrane in Three Ion System

Autor:	Yutaka Hirata, Hitoshi Shinohara, Hideo Kimizuka, Masashi Date, Akira Yamauchi, Makoto Shinoda
Rok vydání:	1987
Předmět:	Matrix (mathematics) Membrane Ion exchange Chemical physics Chemistry Inorganic chemistry Conductance Membrane conductance General Chemistry Ion transfer Alkali metal Ion
Zdroj:	Bulletin of the Chemical Society of Japan. 60:1645-1648
ISSN:	1348-0634 0009-2673
Popis:	A conductance matrix describing the ion-transport phenomena in the membrane-three ion system has been determined. It was indicated there that six independent experiments were required in order to determine six independent elements of the conductance matrix. The NaCl–CaCl2–amphoteric membrane system was chosen as the three ion system, and three kinds of fluxes, two kinds of transport numbers, and the membrane conductance were measured. Nine elements were experimentally determined on the assumption of Onsager’s reciprocal relation. The results showed that the order of elements in conductance matrix was gCaCa>gClCl>gNaNa>gCaCl>gNaCl>gCaNa. In addition, it was pointed out that the interactions among ions can never be ignored when the ion-transport phenomena across membrane are studied.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::79d514faf23470e8b2f16a23c80d4d02 https://doi.org/10.1246/bcsj.60.1645 Zobrazit plný text záznamu