{3-[(E)-(5-Bromo-2-oxidophenyl)methylamino]propanoato-κ3O,N,O′}(1,10-phenanthroline-κ2N,N′)copper(II) dihydrate

Autor:	Zheng Liu, Yuan-Bin Lin, Guang-Zhao Li, Xiao-Zhen Feng, Shu-Hua Zhang
Rok vydání:	2006
Předmět:	Chemistry Hydrogen bond Ligand Phenanthroline chemistry.chemical_element General Chemistry Crystal structure Condensed Matter Physics Copper Crystallography chemistry.chemical_compound Propanoic acid Atom General Materials Science
Zdroj:	Acta Crystallographica Section E Structure Reports Online. 63:m156-m158
ISSN:	1600-5368
Popis:	In the title complex, [Cu(L)(phen)]·2H2O, {LH2 = 3-[(E)-(5-bromo-2-oxidophen­yl)methyl­eneamino]propanoic acid (C10H10BrNO3) and phen = 1,10-phenanthroline (C12H8N2)}, the CuII atom is coordinated in a slightly distorted square-pyramidal geometry by two O atoms and one N atom from an L2− ligand, and two N atoms from a phen ligand. One of the carboxyl­ate O atoms is in the apical position. In the crystal structure, a two-dimensional supra­molecular network is formed through inter­molecular N—H⋯O and O—H⋯O hydrogen bonds.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::79cdc10c26e0bac955783174ef3acc1c https://doi.org/10.1107/s1600536806052500 Zobrazit plný text záznamu Plný text