Anisotropic Molecular Orientation of Poly(o-trimethylsilyl)-Phenylacetylene Film Swollen under High Magnetic Field

Autor: Hiroyuki Niino, Takeo Akiya, Koichi Saito, Shiro Nagata, Kenzo Fukuda, Akira Yabe, Toshiaki Itadani
Rok vydání: 1994
Předmět:
Zdroj: Japanese Journal of Applied Physics. 33:L1475
ISSN: 1347-4065
0021-4922
DOI: 10.1143/jjap.33.l1475
Popis: Poly(o-trimethylsllyl)-phenylacetylene (PTP) film, which was swollen in acetone under a high magnetic field of 15 T, showed birefringence and dichroism. Comparing the IR dichroism of magnetic-field-treated film with that of mechanically stretched film, it was found that the polymer long chain was aligned perpendicularly to the magnetic field. This alignment originated from the magnetic anisotropy of crystalline structures in PTP film.
Databáze: OpenAIRE