3-Trimethylsilyl-3-Buten-2-One as Michael Acceptor for Conjugate Addition-Annelation:cis-4,4a,5,6,7,8-Hexahydro-4a,5-Dimethyl-2(3H)-Naphthalenone

Autor:	David M. Blum, Bruce Ganem, Robert K. Boeckman
Rok vydání:	2003
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Annulation Trimethylsilyl chemistry Iodide Michael reaction Hydroxide Organic chemistry Methyllithium Copper(I) iodide Conjugate
Zdroj:	Organic Syntheses
DOI:	10.1002/0471264180.os058.28
Popis:	3-Trimethylsilyl-3-buten-2-one as michael acceptor for conjugate addition-annelation: cis-4,4a,5,6,7,8-hexahydro-4a,5-dimethyl-2(3H)-naphthalenone product: cis-4,4a,5,6,7,8-HEXAHYDRO-4a,5-DIMETHYL-2(3H)-NAPHTHALENONE Keywords: addition, to CC–CO and CC–CN; annulation, carbocyclic-[6]; cyclization, condensation; assay methods, for methyllithium with 2-butanol, 1,10-phenanthroline or 2,2′-bipydridyl or 2,2′-biquinoline indicator; buffer solutions, ammonium chloride-ammonium hydroxide; copper(I) iodide; distillation, apparatus, Kugelrohr distillation oven
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::799f1edcac7a451963aafc4c4714d175 https://doi.org/10.1002/0471264180.os058.28 Zobrazit plný text záznamu