Self-complexation: the nature for high hydrodesulfurization activity of NiWO4 nanoparticles

Autor:	Qinghe Yang, Hong Nie, Mingfeng Li, Dadong Li, Yunfei Bi, Guofu Xia, Shuangqin Zeng
Rok vydání:	2014
Předmět:	Process Chemistry and Technology Inorganic chemistry Sulfidation chemistry.chemical_element Nanoparticle General Chemistry Tungsten Sulfur containing Catalysis Hydrothermal circulation Nickel chemistry Hydrodesulfurization
Zdroj:	Catalysis Communications. 57:5-8
ISSN:	1566-7367
Popis:	NiWO 4 nanoparticles and two kinds of the precursors were synthesized by a hydrothermal approach and tested for the hydrodesulfurization of sulfur containing organics. Results show that the hydrodesulfurization activity of sulfided NiWO 4 nanoparticles is highest among them. The investigation about the nature for different hydrodesulfurization activities of the catalysts reveals that a simultaneous sulfidation i.e. self-complexation of nickel and tungsten can be observed on NiWO 4 nanoparticles. Furthermore, both temperature-programmed sulfidation and TEM images demonstrated that the self-complexation is originated from the special structure and size of NiWO 4 nanoparticles. These results show a promising potential to develop efficient hydrotreatment catalyst.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::799aac8dbc2724003ec4b26562a0ed1b https://doi.org/10.1016/j.catcom.2014.07.021 Zobrazit plný text záznamu Full Text from ScienceDirect