Consolidation of Tin Sulfide Chalcogels and Xerogels with and without Adsorbed Iodine

Autor:	Aneeruddha Bulbule, William C. Lepry, Edward M. Sabolsky, Fares Khamis Alblouwy, Kota S. Subrahmanyam, Brian J. Riley, Jared O. Kroll, David A. Pierce, Mercouri G. Kanatzidis, Jaehun Chun
Rok vydání:	2015
Předmět:	Materials science Consolidation (soil) General Chemical Engineering Inorganic chemistry Chalcogenide glass chemistry.chemical_element General Chemistry Iodine Industrial and Manufacturing Engineering Chalcogel Adsorption chemistry Chemisorption Hot isostatic pressing Tin sulfide
Zdroj:	Industrial & Engineering Chemistry Research. 54:11259-11267
ISSN:	1520-5045 0888-5885
DOI:	10.1021/acs.iecr.5b02697
Popis:	Tin sulfide (Sn2S3) chalcogels are one of the most effective nonoxide aerogels evaluated to date for iodine gas capture. This is attributed to the fact that the Sn within the gel network has a strong affinity for chemisorption of iodine to form SnI4. This study demonstrates an approach for consolidating the raw and iodine-sorbed Sn2S3 chalcogels into a chalcogenide glass using GeS2 as a glass-forming additive. Adding GeS2 to iodine-sorbed or iodine-free Sn2S3 chalcogels provides better glass formation than Sn–S or Sn–S–I alone, and the quantity of iodine measured in the bulk glass of the consolidated iodine-sorbed Sn2S3 chalcogel was at ∼45 mass%. Additional experiments were conducted using microwave sintering and hot isostatic pressing with iodine-sorbed Sn2S3 xerogels to evaluate alternative consolidation techniques.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::799384bc3461ec82176afe71d74c8535 https://doi.org/10.1021/acs.iecr.5b02697 Zobrazit plný text záznamu