Leaching Kinetics of Bauxite in Hydrochloric Acid

Autor: D. H. Jenkins, H. N. Sinha
Rok vydání: 1995
Předmět:
Zdroj: Mineral Processing and Extractive Metallurgy Review. 15:143-143
ISSN: 1547-7401
0882-7508
DOI: 10.1080/08827509508914168
Popis: The Bayer process is currently used to produce cell-grade alumina from bauxite. However, if the reactive silica content in the bauxite exceeds 7%, losses of caustic and aluminium as sodalite (2 Na20.2 Al2O3·3 SiO2·2 H2O) become economically unacceptable. As Australia possesses large tonnages of bauxite containing more than 7% reactive silica, a process for the production of cell-grade alumina horn these bauxites using hydrochloric acid leaching was developed by the authors. The process consists of the following steps: calcination of bauxite, leaching of calcined bauxite in hydrochloric acid, filtration of residue, crystallization of A1C13.6 H2O, decomposition of AlCl3.6 H2O crystals to produce A12O3, regeneration of hydrochloric acid for recycle into the leaching step. The kinetic studies of the dissolution showed that the extraction of aluminium is independent of the solid to leachant ratios studied. The acid concentration has a marked effect on leaching kinetics of bauxite and the leaching time decrease...
Databáze: OpenAIRE