Nickel(ii) N-heterocyclic carbene complexes as efficient catalysts for the Suzuki—Miyaura reaction

Autor:	Alexander V. Astakhov, Safarmurod B. Soliev, Dmitry V. Pasyukov, Victor M. Chernyshev
Rok vydání:	2020
Předmět:	Benzimidazole 010405 organic chemistry Aryl Halide chemistry.chemical_element General Chemistry 010402 general chemistry 01 natural sciences 0104 chemical sciences Catalysis chemistry.chemical_compound Nickel chemistry Polymer chemistry Imidazole Carbene Palladium
Zdroj:	Russian Chemical Bulletin. 69:683-690
ISSN:	1573-9171 1066-5285
Popis:	Catalytic activity of nickel(ii) and palladium(ii) N-heterocyclic carbene (NHC) complexes derived from imidazole, benzimidazole, and 1,2,4-triazole was comparatively evaluated in the cross-coupling reactions of aryl halides with arylboronic acids. Readily available nickel bis-NHC complexes (NHC)2NiX2 (X = Cl, Br, or I) exhibited the activity comparable to that of the structurally related palladium complexes and, consequently, can be applied as efficient catalysts for the Suzuki—Miyaura reaction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::798eda850e9550d576ded60796366f8c https://doi.org/10.1007/s11172-020-2818-3 Zobrazit plný text záznamu Full text from SpringerLink