Synthesis, physicochemical properties, and structural isomerism of cadmium chloride coordination compounds with ɛ-caprolactam
| Autor: | A. V. Virovets, E. S. Tatarinova, Yu. R. Giniyatullina, T. G. Cherkasova, Eugenia V. Peresypkina |
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| Rok vydání: | 2015 |
| Předmět: |
chemistry.chemical_classification
Stereochemistry Coordination polymer Materials Science (miscellaneous) Thermal decomposition Caprolactam Infrared spectroscopy Cadmium chloride Coordination complex Inorganic Chemistry chemistry.chemical_compound Crystallography chemistry Structural isomer Physical and Theoretical Chemistry Monoclinic crystal system |
| Zdroj: | Russian Journal of Inorganic Chemistry. 60:46-50 |
| ISSN: | 1531-8613 0036-0236 |
| Popis: | Two new differently structured cadmium(II) coordination polymers (I and II) of the same composition Cd(Cpl)Cl2 (Cpl is ɛ-caprolactam) were synthesized. Their structure was characterized by IR spectroscopy and X-ray diffraction. Crystals of compounds I and II were monoclinic, space group P21/c, a = 10.0551(6) A, b = 15.2035(11) A, c = 6.6079(3) A, β = 108.462(2)°, V = 958.18(10) A3, ρcalcd = 2.055 g/cm3, Z = 4 for I and a = 6.66620(10) A, b = 18.9061(4) A, c = 15.5188(3) A, β = 96.8640(10)°, V = 1941.84(6) A3, ρcalcd = 2.028 g/cm3, Z = 8 for II. The thermolysis of compound I was studied thermogravimetrically. |
| Databáze: | OpenAIRE |
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