Co-N-doped carbon nanotubes supported on diatomite for highly efficient catalysis oxidative carbonylation of amines with CO and air
| Autor: | Qinwei Yu, Jian Lu, Dong-huai Tu, Jiangwei Li, Li Yani, Wang Weiqiang, Jianming Yang |
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| Rok vydání: | 2018 |
| Předmět: |
inorganic chemicals
010405 organic chemistry Process Chemistry and Technology Inorganic chemistry chemistry.chemical_element Homogeneous catalysis Carbon nanotube 010402 general chemistry 01 natural sciences Catalysis 0104 chemical sciences law.invention chemistry.chemical_compound chemistry law Oxidizing agent Organic chemistry Phosgene Selectivity Carbonylation Palladium |
| Zdroj: | Applied Catalysis A: General. 549:112-116 |
| ISSN: | 0926-860X |
| DOI: | 10.1016/j.apcata.2017.09.030 |
| Popis: | Cobalt-nitrogen-doped carbon nanotubes stably supported on diatomite were obtained by employing Co(OAc)2/phenanthroline. The resulting material was found to be excellent catalysts for the carbonylation of a variety of amines with CO other than phosgene. Both high activity and selectivity were achieved in this carbonylation process, and it allows air as a cheap oxidizing agent. Moreover the catalyst could be recycled for several times with relatively higher activity compared to homogeneous catalyst palladium acetate. |
| Databáze: | OpenAIRE |
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