Macrokinetics of physicochemical condensation in two-phase systems of the gas-solid body type

Autor:	I. A. Filimonov, Yu. M. Grigor'ev, S. I. Doronin
Rok vydání:	1998
Předmět:	Chemistry General Chemical Engineering Condensation Microscopic level Evaporation General Physics and Astronomy Energy Engineering and Power Technology Thermodynamics General Chemistry Gas solid Body type Isothermal process Fuel Technology Phase (matter) Equilibrium constant
Zdroj:	Combustion, Explosion, and Shock Waves. 34:280-287
ISSN:	1573-8345 0010-5082
DOI:	10.1007/bf02672718
Popis:	The macrokinetics of the phase evolution at the microscopic level under isothermal and nonisothermal conditions is analyzed theoretically within the framework of a two-scale approach for describing physicochemical condensation processes in two-phase systems. Scenarios are established for the transformation of the condensed particles in a chemically active medium, taking into account the exothermal nature of the reaction, the finiteness of heat- and mass-transfer rates, and the phase transformations. The equilibrium constant of the heterogeneous reactions is shown to have a significant effect on the conditions of evaporation, or the increase in the incipient condensation phase. An analytical criterion is obtained for controlling the phase transformation in a reaction-capable medium, and it is supported by numerical calculations.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::796bda34a31fdb9359bb05e7434b09c6 https://doi.org/10.1007/bf02672718 Zobrazit plný text záznamu Full text from SpringerLink