Synthesis of Biphenyloferrocenophanes
| Autor: | Taeko Izumi, I. Shimizu, Takeshi Tezuka, Akira Kasahara, Yoshio Kamei |
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| Rok vydání: | 1983 |
| Předmět: | |
| Zdroj: | Bulletin of the Chemical Society of Japan. 56:192-198 |
| ISSN: | 1348-0634 0009-2673 |
| Popis: | Some ferrocenophanes, in which the two cyclopentadienyl rings are linked by biphenyl rings, have been synthesized via intramolecular reductive coupling of the corresponding formyl compounds with a low-valent titanium reagent. The structures of these cyclophane compounds were determined by IR, NMR, and UV spectra analyses. Transannular π-electronic interactions between the two biphenyl rings were examined on the basis of electronic spectra. |
| Databáze: | OpenAIRE |
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