Elimination reactions of ions in the gas phase. V—elimination of water in hydroxybornanes and related compounds

Autor:	D. Kovačević, Richard Robbiani, J. Seibl, A. Fraefel, H. Bührer, H. Mändli
Rok vydání:	1978
Předmět:	Cleavage (embryo) Ring (chemistry) Biochemistry Medicinal chemistry Ion Borneol Elimination reaction chemistry.chemical_compound Stereospecificity Deuterium chemistry Labelling Molecular Medicine Organic chemistry Instrumentation Spectroscopy
Zdroj:	Organic Mass Spectrometry. 13:275-279
ISSN:	1096-9888 0030-493X
DOI:	10.1002/oms.1210130509
Popis:	Results of an investigation of deuterium labelled methylated norborneols and dihydrocarveols are presented to show that the 1,2 elimination of water in borneol and isoborneol is triggered by an initial ring cleavage reaction. Other eliminations of water in borneol and isoborneol are elucidated by specific and stereospecific deuterium labelling in different positions.
Databáze:	OpenAIRE
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