Preparação de compostos lamelares: síntese do hidrogenofosfato de zircônio cristalino e sua intercalação com aminas. Um experimento para estudantes de graduação

Autor:	Yoshitaka Gushikem, William S. Cardoso
Rok vydání:	2005
Předmět:	Zirconium chemistry.chemical_compound Solid structure chemistry Stereochemistry Precipitation (chemistry) Intercalation (chemistry) Pyridine Polymer chemistry chemistry.chemical_element Lamellar structure General Chemistry Hydrogen phosphate
Zdroj:	Química Nova. 28:723-726
ISSN:	0100-4042
DOI:	10.1590/s0100-40422005000400029
Popis:	The present paper describes the synthesis of crystalline zirconium hydrogen phosphate by direct precipitation and its intercalation with pyridine and n-butylamine. The simple experiment was tested in the undergraduate inorganic chemistry laboratory course for chemistry students at IQ-UNICAMP using inexpensive reagents. The materials were characterized by powder X-ray diffraction and infrared analyses in order to obtain detailed information of the solid structure changes as a result of the intercalation process. Pyridine and n-butylamine are focused in this work as clear and elucidative examples leading to acid-base interactive processes that result in the well-formed infinite sequence of inorganic lamellar structures.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::791dff7a5ca5f7cb0b457a999c33b938 https://doi.org/10.1590/s0100-40422005000400029 Zobrazit plný text záznamu