THE EFFECTS OF ALLYL ETHERS UPON RADICAL POLYMERIZATIONS

Autor:	Barry J. Hunt, Thomas N. Huckerby, Aubrey D. Jenkins, John C. Bevington
Rok vydání:	2001
Předmět:	Polymers and Plastics Radical polymerization technology industry and agriculture Azobisisobutyronitrile food and beverages Solution polymerization Ether macromolecular substances General Chemistry Styrene chemistry.chemical_compound chemistry Polymer chemistry Materials Chemistry Ceramics and Composites Copolymer Methyl methacrylate Acrylonitrile
Zdroj:	Journal of Macromolecular Science, Part A. 38:627-640
ISSN:	1060-1325
DOI:	10.1081/ma-100103869
Popis:	Three allyl ethers, viz. the ethyl, 2-hydroxyethyl and phenyl compounds, have been examined as additives in radical polymerizations of styrene (STY), methyl methacrylate (MMA) and acrylonitrile (ACN) at 60°C using azobisisobutyronitrile as initiator. As retarders and transfer agents, the ethers are considerably more effective with ACN than with the other monomers. Allyl phenyl ether engages in significant copolymerization with ACN and slight copolymerization with MMA; there is negligible incorporation in polySTY.
Databáze:	OpenAIRE
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