SnO2–SiO2 Mesoporous Composite: A Very Active Catalyst for Regioselective Synthesis of Aromatic Ketones with Unusual Catalytic Behavior

Autor:	Suresh K. Bhargava, Pavuluri Srinivasu, M. Lakshmi Kantam, K. Raveendranath Reddy, Dupati Venkanna
Rok vydání:	2015
Předmět:	chemistry.chemical_classification General Chemical Engineering Aryl Composite number Aromatic ketones Halide Regioselectivity General Chemistry Industrial and Manufacturing Engineering Catalysis chemistry.chemical_compound chemistry Organic chemistry Mesoporous material Alkyl
Zdroj:	Industrial & Engineering Chemistry Research. 54:7005-7013
ISSN:	1520-5045 0888-5885
DOI:	10.1021/acs.iecr.5b00910
Popis:	Aromatic ketones (R-Ar-CO-R′) have been prepared directly through C–C bond formation using aromatics, aryl, and alkyl acid halides in a Friedel–Crafts reaction over a reusable and catalytically active ordered SnO2–SiO2 three-dimensional mesoporous composite (PS-4) catalyst, which was found to be superior to modified zeolites, functionalized MCM-41, and supported heteropolyacid catalysts.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::78de334cc326026c70438abd2b7b09de https://doi.org/10.1021/acs.iecr.5b00910 Zobrazit plný text záznamu