Reactivity of dioxygen with manganese Schiff-base complexes: a chemical and electrochemical investigation

Autor:	Cuixia Liu, Colin P. Horwitz, Yangzhen Ciringh, Samantha Park
Rok vydání:	1993
Předmět:	Schiff base Inorganic chemistry chemistry.chemical_element Manganese Electrochemistry Medicinal chemistry Oxygen Inorganic Chemistry chemistry.chemical_compound chemistry Propane Reactivity (chemistry) Physical and Theoretical Chemistry Cyclic voltammetry Acetonitrile
Zdroj:	Inorganic Chemistry. 32:5951-5956
ISSN:	1520-510X 0020-1669
DOI:	10.1021/ic00078a010
Popis:	The bis(μ-oxo) dimers [(X-SALPRN)Mn IV (μ-O)] 2 , where X=5-Cl, 1c, 3,5-Cl 2 , 2c, and 5-CH 3 O, 3c, and SALPRN is 1,3-bis(salicylideneamino)propane, were prepared by two routes: oxidation of (X-SALPRN)Mn II , X=5-Cl, 1b, 3,5-Cl 2 , 2b, and 5-CH 3 O, 3b, with O 2 in acetonitrile or bulk electrochemical reduction of the Mn(III) salt, [(X-SALPRN)Mn III ] PF 6 , X=5-Cl, 1a, 3,5-Cl 2 , 2a, and 5-CH 3 O, 3a, in the presence of dioxygen in 0.2 M TBAPF 6 /CH 3 CN
Databáze:	OpenAIRE
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