Thermodynamic viscous flow activation characteristics for n-alkanes and n-alkanes-1
| Autor: | A. A. Rudnitskaya, Yu. Ya. Fialkov, I. A. Renskii |
|---|---|
| Rok vydání: | 2003 |
| Předmět: |
Fluid viscosity
N alkanes Chemistry Intermolecular force Thermodynamics Condensed Matter Physics Kinetic energy Atomic and Molecular Physics and Optics Electronic Optical and Magnetic Materials Physics::Fluid Dynamics Transition state theory General theory Viscous flow Materials Chemistry Physics::Chemical Physics Physical and Theoretical Chemistry Spectroscopy |
| Zdroj: | Journal of Molecular Liquids. 105:73-78 |
| ISSN: | 0167-7322 |
| DOI: | 10.1016/s0167-7322(03)00013-8 |
| Popis: | The paper presents viscous flow activation parameters for n-alkanes and n-alkens-1, calculated from the equation of transition state theory. Transmission coefficients and true values of the entropy of viscous flow activation of n-alkanes and n-alkens-1 have been calculated from kinetic compensation effects using theses of the Shakhparonov general theory of fluid viscosity. Analysis of the data obtained allows one to conclude that the intermolecular interactions caused by weak CσH…Cσ bonds are more pronounced is saturated hydrocarbons. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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