ChemInform Abstract: A Salt-Free Synthesis of 1,2-Bisphosphorylethanes via an Efficient PMe3-Catalyzed Addition of
Autor:
Akiya Ogawa, Li-Biao Han, Yuta Saga, Daoqing Han, Shinichi Kawaguchi
Rok vydání:
2016
Předmět:
Zdroj:
ChemInform. 47
ISSN:
0931-7597
DOI:
10.1002/chin.201602169
Popis:
A convenient and versatile method was developed for the preparation of 1,2-bisphosphorylethanes. Thus, in the presence of a catalytic amount of trimethylphosphine, a variety of >P(O)H compounds efficiently add to vinylphosphoryl compounds to produce the corresponding 1,2-bisphosphorylethanes in high yields. In most cases, the trimethylphosphine catalyst was simply removed under vacuum leaving spectroscopically pure adducts. The present method provided a halogen and metal-free clean process for the preparation of 1,2-bisphosphorylethanes.
Databáze:
OpenAIRE
Externí odkaz:
| Autor: | Akiya Ogawa, Li-Biao Han, Yuta Saga, Daoqing Han, Shinichi Kawaguchi |
|---|---|
| Rok vydání: | 2016 |
| Předmět: | |
| Zdroj: | ChemInform. 47 |
| ISSN: | 0931-7597 |
| DOI: | 10.1002/chin.201602169 |
| Popis: | A convenient and versatile method was developed for the preparation of 1,2-bisphosphorylethanes. Thus, in the presence of a catalytic amount of trimethylphosphine, a variety of >P(O)H compounds efficiently add to vinylphosphoryl compounds to produce the corresponding 1,2-bisphosphorylethanes in high yields. In most cases, the trimethylphosphine catalyst was simply removed under vacuum leaving spectroscopically pure adducts. The present method provided a halogen and metal-free clean process for the preparation of 1,2-bisphosphorylethanes. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
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