Static Permittivity and Association in Mixtures of Mono- and Dihydric Alcohols

Autor: A. H. Shafik, M. Stockhausen, F. F. Hanna
Rok vydání: 1995
Předmět:
Zdroj: Zeitschrift für Naturforschung A. 50:785-786
ISSN: 1865-7109
0932-0784
DOI: 10.1515/zna-1995-0812
Popis: The static permittivity has been measured for n-hexanol and n-dodecanol in heptane solution on admixture of a mi­ nor (fixed) fraction of a dihydric alcohol (ethanediol, 1,6-hexanediol or 1,12-dodecanediol) from low to medium total alcohol concentrations. The 20°C dispersion steps are re­ ported. They show a more or less pronounced intensification due to the additive, which unexpectedly is smaller on addi­tion of two diols together than of only one diol. Probably this reflects competing self- and hetero-association equilibria.
Databáze: OpenAIRE