Synthesis of penta- and tetra-cyclic cage-like compounds and dispiro heterocycles through microwave-assisted solvent-free multi-component domino reactions
| Autor: | Anitha Kandasamy, Abdulrahman I. Almansour, S. Maharani, Raju Suresh Kumar, Sundaravel Vivek Kumar, Raju Ranjith Kumar |
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| Rok vydání: | 2017 |
| Předmět: |
Solvent free
Sarcosine biology 010405 organic chemistry Component (thermodynamics) General Chemistry 010402 general chemistry biology.organism_classification 01 natural sciences Microwave assisted Catalysis Domino 0104 chemical sciences Solvent chemistry.chemical_compound chemistry Ninhydrin Materials Chemistry Tetra Organic chemistry |
| Zdroj: | New Journal of Chemistry. 41:11009-11015 |
| ISSN: | 1369-9261 1144-0546 |
| Popis: | Novel penta- and tetra-cyclic cage-like compounds and dispiro heterocycles were obtained as a result of the microwave-assisted three-component domino reactions of heterocyclic or carbocyclic ketones, ninhydrin and sarcosine under solvent- and catalyst-free conditions. Interestingly, heterocyclic ketones afforded fused polycyclic cage-like compounds, whereas the carbocyclic ketones led to the formation of dispiro heterocycles. |
| Databáze: | OpenAIRE |
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