Synthesis and crystallization of lithium-yttrium orthoborate Li6Y(BO3)3 phase

Autor:	K. Polgár, Ágnes Péter, M. Tóth
Rok vydání:	2012
Předmět:	Materials science chemistry.chemical_element Yttrium Condensed Matter Physics Dissociation (chemistry) law.invention Inorganic Chemistry Crystallography Chemical engineering chemistry law visual_art Materials Chemistry visual_art.visual_art_medium Ceramic Crystallization Supercooling Phase analysis
Zdroj:	Journal of Crystal Growth. 346:69-74
ISSN:	0022-0248
Popis:	Single crystals of Li6Y(BO3)3 have been grown by both the Bridgman and Czochralski methods. It was found that the complex nature of the melt solidification s affects the efficiency of the crystallization process and the composition of the grown crystals. High supercooling favored melt dissociation and the formation of thermodynamically unstable phases Li3Y(BO3)2 and Li3Y2(BO3)3. Applying X-ray phase analysis for air-quenched ceramic samples it was shown that the room temperature stability region of the off–stoichiometric Li6Y(BO3)3 phase is extended towards the B2O3 rich, Y2O3 deficient compositions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7816a2737f62b11e20b43ae2122d2956 https://doi.org/10.1016/j.jcrysgro.2012.02.034 Zobrazit plný text záznamu Full Text from ScienceDirect