Evidence for a lowest energy 3MLCT excited state in [Fe(tpy)(CN)3]−
| Autor: | Elena Jakubikova, Sebastian B. Vittardi, Rajani Thapa Magar, Christopher J Ziegler, Briana R Schrage, Jeffrey J. Rack |
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| Rok vydání: | 2021 |
| Předmět: |
Component (thermodynamics)
Chemistry Cyanide Metals and Alloys General Chemistry Kinetic energy Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound Excited state Ultrafast laser spectroscopy Materials Chemistry Ceramics and Composites Physical chemistry Energy (signal processing) |
| Zdroj: | Chemical Communications. 57:4658-4661 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/d1cc01090e |
| Popis: | Transient absorption data of [FeII(tpy)(CN)3]- reveals spectroscopic signatures indicative of 3MLCT with a ∼10 ps kinetic component. These data are supported by DFT and TD-DFT calculations, which show that excited state ordering is responsive to the number of cyanide ligands on the complex. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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