Very-low temperature magnetic ordering and dimensionality of the square planar system cobalt(II) phenoxyacetate

Autor: Jean-Michel Rueff, Marc Drillon, Carley Paulsen, Pierre Rabu, J. Souletie
Rok vydání: 2005
Předmět:
Zdroj: Solid State Sciences. 7:431-436
ISSN: 1293-2558
DOI: 10.1016/j.solidstatesciences.2005.01.005
Popis: The magnetic behaviour of the layered compound [Co(O2C(CH2)OC6H5)2(H2O)2]n (1) has been fully analysed, in the temperature range 150 mK to 300 K. The compound exhibits below 10 K a ferromagnetic-like behaviour and a long-range order at T C = 0.57 K . The magnetic dimensionality has been analysed by using scaling approach. The high temperature behaviour is well described by an exponential law while in the vicinity of T C a power law variation is characteristic of a 2D to 3D crossover. The critical exponent γ = 1.26 deduced by fitting the experimental data above T C agrees well with that expected for an Ising system.
Databáze: OpenAIRE