Factors Associated with Accurate Analysis of Fischer–Tropsch Products

Autor:	Kang Xiao, Xinxing Wang, Dong Lv, Mingxiong Zhu, Qi Xingzhen, Liangshu Zhong
Rok vydání:	2017
Předmět:	010405 organic chemistry business.industry Chemistry Physical separation Fischer–Tropsch process Fraction (chemistry) General Chemistry 010402 general chemistry Process engineering business 01 natural sciences Catalysis 0104 chemical sciences
Zdroj:	Catalysis Letters. 147:704-715
ISSN:	1572-879X 1011-372X
Popis:	Accurate analysis of Fischer–Tropsch (FT) products is very important for reaction mechanism and kinetics studies. However, it is rather complex since many factors in collecting, measurement and GC analysis have influences on the results. These factors should be considered in research to avoid possible artifacts. In this paper, some issues and considerations in FT products analysis were discussed. To obtain reliable results, it is recommended to collect samples after the steady state of the reaction reached without further catalyst reconstruction and net products accumulation. Products collection fraction should be in acceptable range besides commonly calculated balances. The physical separation of different phases of products should be as complete as possible and the identification of different products in GC analysis should be checked carefully.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::77e68921e476b5c24e2ef6d48cef12a5 https://doi.org/10.1007/s10562-016-1958-4 Zobrazit plný text záznamu Plný text ve formátu PDF