Comparative study of the surface oxide films on lean duplex and corresponding single phase stainless steels by XPS and ToF-SIMS
Autor: | Philippe Marcus, Audrey Allion-Maurer, Sandrine Zanna, Antoine Seyeux, Elise Gardin |
---|---|
Rok vydání: | 2018 |
Předmět: |
inorganic chemicals
Materials science 020209 energy General Chemical Engineering Inorganic chemistry technology industry and agriculture Oxide chemistry.chemical_element 02 engineering and technology General Chemistry 021001 nanoscience & nanotechnology Corrosion Metal chemistry.chemical_compound Chromium Nickel chemistry X-ray photoelectron spectroscopy Molybdenum visual_art 0202 electrical engineering electronic engineering information engineering visual_art.visual_art_medium General Materials Science 0210 nano-technology Layer (electronics) |
Zdroj: | Corrosion Science. 143:403-413 |
ISSN: | 0010-938X |
DOI: | 10.1016/j.corsci.2018.08.009 |
Popis: | The surface oxide films formed after mechanical polishing on duplex stainless steel and corresponding single phase alloys were characterized by XPS and ToF-SIMS. The native oxide films are mixtures of oxides and hydroxides composed of Fe(III), Mo(IV) and Mo(VI) in the outer region and Cr(III) in the inner region. Nickel, molybdenum and nitrogen are enriched in the underlying metal while chromium and molybdenum are enriched in the oxide layer. The contents of alloying elements in the oxide layer and/or in the underlying metal are found to be directly related to their content in the bulk of the alloys. |
Databáze: | OpenAIRE |
Externí odkaz: |