ChemInform Abstract: Sonochemical Synthesis of 1,1-Dimethyl-1-germacyclopent-3-enes and the Extrusion of Dimethylgermylene Upon Their Pyrolysis

Autor:	Peter P. Gaspar, Deqing Lei
Rok vydání:	2010
Předmět:	chemistry Chemical engineering chemistry.chemical_element Organic chemistry Extrusion Lithium General Medicine Pyrolysis
Zdroj:	ChemInform. 22
ISSN:	0931-7597
DOI:	10.1002/chin.199140203
Popis:	The ultrasound-promoted reaction of dichlorodimethylgermane with lithium in the presence of substituted 1,3-dienes results in the formation of the corresponding germacyclopent-3-enes in good yields. The gas-phase flow pyrolysis of 1,1,3-trimethyl- and 1,1,3,4-tetramethyl-1-germacyclopent-3-enes leads to the extrusion of dimethylgermylene that has been trapped by addition to 1,3-dienes.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::77c8e83e6439f1eb60c8eb754441419d https://doi.org/10.1002/chin.199140203 Zobrazit plný text záznamu Plný text