Rhodium Hydrogenation Catalysts Supported in Metal Organic Frameworks: Influence of the Framework on Catalytic Activity and Selectivity
| Autor: | Laura Y. Pfund, Melanie S. Sanford, Adam J. Matzger, Douglas T. Genna, Danielle C. Samblanet, Antek G. Wong-Foy |
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| Rok vydání: | 2016 |
| Předmět: |
chemistry.chemical_classification
Ion exchange 010405 organic chemistry Alkene Cationic polymerization chemistry.chemical_element Substrate (chemistry) General Chemistry 010402 general chemistry 01 natural sciences Catalysis 0104 chemical sciences Rhodium chemistry Organic chemistry Metal-organic framework Selectivity |
| Zdroj: | ACS Catalysis. 6:3569-3574 |
| ISSN: | 2155-5435 |
| DOI: | 10.1021/acscatal.6b00404 |
| Popis: | The cationic rhodium complexes (dppe)Rh(COD)BF4 and (MeCN)2Rh(COD)BF4 have been supported in metal–organic frameworks bearing anionic nodes (ZJU-28) and anionic linkers (MIL-101-SO3) via ion exchange. These MOF-supported Rh species serve as recyclable catalysts for the hydrogenation of both the terminal alkene substrate 1-octene and the internal alkene substrate 2,3-dimethylbutene. The nature of the MOF support impacts various aspects of catalysis, including: (i) the rate of 1-octene hydrogenation, (ii) the activity and recyclability of the catalyst in 2,3-dimethylbutene hydrogenation, and (iii) the size selectivity of hydrogenation with alkene substrates appended to calixarenes. |
| Databáze: | OpenAIRE |
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