GC/MSD detection of the metabolic residues of metolachlor in tomato fruit

Autor:	J. D. Gaynor, D. C. MacTavish, A. S. Hamill
Rok vydání:	1992
Předmět:	Detection limit Chromatography Organic Chemistry Clinical Biochemistry Method of analysis Pesticide Mass spectrometry Biochemistry Analytical Chemistry Hydrolysis chemistry.chemical_compound chemistry Acid hydrolysis Gas chromatography Metolachlor
Zdroj:	Chromatographia. 33:147-150
ISSN:	1612-1112 0009-5893
DOI:	10.1007/bf02275895
Popis:	A gas chromatograph/mass selective detector method is presented for the analysis of the major metabolic residues of metolachlor by acid hydrolysis of tomato fruit. The two major hydrolysis products, CGA-37913 (2-[2-ethyl-6-methylphenyl]amino-1-propanol) and derivatised CGA-49751 (4-[2-ethyl-6-methylphenyl]-2-hydroxy-5-methyl-3-morpholinone) were monitored in the selective ion mode atm/z 162 andm/z 160, respectively. Recoveries from 87 to 96% were obtained for tomato fortified at 50 to 200μg kg−1. The proposed method of analysis will allow for a detection limit of 11 μg kg−1 for CGA-37913 and 12 μg kg−1 for the derivatised CGA-49751.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::77b5e415f8476d568ce2b68e6d553057 https://doi.org/10.1007/bf02275895 Zobrazit plný text záznamu Full text from SpringerLink