Novel Photocycloaddition of Aromatic Ketones to Cyclic Oligosilanes

Autor: Kazuhiro Kondo, Masanobu Wakasa, Hisaharu Hayashi, Masahiro Kako, Mei Gu, Yohei Takenaka, Yasuhiro Nakadaira, Kentaro Takagi
Rok vydání: 2001
Předmět:
Zdroj: Chemistry Letters. 30:1220-1221
ISSN: 1348-0715
0366-7022
DOI: 10.1246/cl.2001.1220
Popis: Photolysis of aromatic ketones (2,2,2-trifluoroacetophenone, acetophenone, and benzophenone) in the presence of cyclic oligosilanes afforded two types of cycloadducts depending on the nature of the ketone employed. The quenching of the excited triplet state of benzophenone by oligosilanes was investigated by laser flash photolysis.
Databáze: OpenAIRE