Synthesis and characterisation of Schiff base macrocyclic Pb(II), Zn(II), Cd(II) and La(III) complexes by template reaction of (±)-trans-1,2-diaminocyclohexane with metal nitrates and salicylaldehyde derivatives

Autor:	Salih Ilhan
Rok vydání:	2009
Předmět:	chemistry.chemical_compound Template reaction Schiff base chemistry Salicylaldehyde Elemental analysis trans-1 2-Diaminocyclohexane Mass spectrum Organic chemistry Molar conductivity General Chemistry Electrolyte Nuclear chemistry
Zdroj:	Journal of Chemical Research. 2009:766-769
ISSN:	2047-6507 1747-5198
DOI:	10.3184/030823409x12596000099172
Popis:	Eight macrocyclic complexes have been synthesised by template reaction of (±)- trans-1,2-diaminocyclohexane with metal nitrates and 1,10-bis(2-formylphenyl)-1,4,7,10-tetraoxadecane or 1,7-bis(2-formylphenyl)-1,4,7-trioxaheptane, and their structures are proposed on the basis of elemental analysis, FT-IR, UV-Vis, molar conductivity measurements, 1H The complexes NMR and mass spectra. The metal-to-ligand molar ratios are 1:1 in the complexes, which are 1:2 electrolytes for Pb(II), Cd(II) and Zn(II) and 1:3 electrolytes for La(III)
Databáze:	OpenAIRE
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