ChemInform Abstract: PULSE RADIOLYSIS STUDY OF MONOVALENT CADMIUM, COBALT, NICKEL AND ZINC IN AQUEOUS SOLUTION. PART 2. REACTIONS OF THE MONOVALENT IONS

Autor:	George V. Buxton, David R. McCracken, Robin M. Sellers
Rok vydání:	1976
Předmět:	chemistry.chemical_classification Cadmium Olefin fiber Electron transfer Aqueous solution chemistry Metal ions in aqueous solution Inorganic chemistry Radiolysis chemistry.chemical_element General Medicine Zinc Electron acceptor
Zdroj:	Chemischer Informationsdienst. 7
ISSN:	0009-2975
DOI:	10.1002/chin.197628020
Popis:	Reactions of the monovalent metal ions Cd+, Co+, Ni+ and Zn+ with electron acceptors in neutral aqueous solution have been studied and three types identified: (a) addition M++ O2→ MO+2(M = Ni) M++ olefin →(M—olefin)+(b) oxygen atom transfer M++ N2O → MO++ N2(c) electron transfer M++ S2O2–8→ M2++ SO–4+ SO2–4. In reaction (b) when M= Co, long lived CoIII species are produced.Evidence is also presented for the oxidation of Co2+ by OH (k= 8 × 105 dm3 mol–1 s–1) and by SO–4(k∼ 2 × 106 dm3 mol–1 s–1) in neutral solution.
Databáze:	OpenAIRE
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