Synthesis and characterization of hypercoordinated germanium complexes with hydroxyalkylethylenediamines
| Autor: | Maxim Y. Arsent'ev, Dmitrii Antuganov, Andrey A. Zolotarev, Valerii L. Ugolkov, Igor S. Ignatyev, Yulia A. Kondratenko, Denis V. Lezov, T. A. Kochina |
|---|---|
| Rok vydání: | 2022 |
| Předmět: |
Organic Chemistry
Intermolecular force chemistry.chemical_element Germanium Ethylenediamine Nuclear magnetic resonance spectroscopy Crystal structure Atmospheric temperature range Biochemistry Inorganic Chemistry Crystallography chemistry.chemical_compound chemistry Elemental analysis Materials Chemistry Physical and Theoretical Chemistry Germanium oxide |
| Zdroj: | Journal of Organometallic Chemistry. 958:122188 |
| ISSN: | 0022-328X |
| Popis: | New germatranes 1-3 were synthesized by the interaction of germanium oxide with N-(2-hydroxyethyl)ethylenediamine (complex 1), N,N,N'N’-tetrakis(2-hydroxyethyl)ethylenediamine (complex 2) and N,N,N'N’-tetrakis(2-hydroxypropyl)ethylenediamine (complex 3). Their composition was confirmed by the data of elemental analysis, IR, UV/Vis and NMR spectroscopy. The thermal behavior of synthesized complexes 1-3 was studied in the temperature range 40-600°C. The crystal structure of compound 2 was determined using single-crystal X-ray diffraction. The Hirschfeld surface analysis was performed to quantify the intermolecular contacts present within the crystal structure of complex 2. The equilibrium structures of the synthesized compounds 1-3 were calculated using DFT methods. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect