Ion-polymer interactions in gel electrolytes studied by ESR spectroscopy of spin probes and spin labels
Autor: | D. Berstan, M. Y. Qureshi, G. Gordon Cameron, Malcolm D. Ingram, C. Rousselot |
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Rok vydání: | 1998 |
Předmět: |
chemistry.chemical_classification
Polymers and Plastics Organic Chemistry Inorganic chemistry Analytical chemistry Concentration effect Salt (chemistry) Poly(methyl methacrylate) Lithium perchlorate chemistry.chemical_compound chemistry visual_art Propylene carbonate Materials Chemistry visual_art.visual_art_medium Ionic conductivity Methyl methacrylate Spectroscopy |
Zdroj: | Polymer International. 47:16-19 |
ISSN: | 1097-0126 0959-8103 |
DOI: | 10.1002/(sici)1097-0126(199809)47:1<16::aid-pi18>3.0.co;2-b |
Popis: | Ion-conducting gels containing poly(methyl methacrylate), propylene carbonate and lithium perchlorate have been studied by ESR spectroscopy using spin-probe and spin-label techniques. Trends in T 50G with increasing salt concentration observed with different polymer contents are indicative of strong cation-matrix interactions which may restrict cation mobility in these systems. |
Databáze: | OpenAIRE |
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