Ion-polymer interactions in gel electrolytes studied by ESR spectroscopy of spin probes and spin labels

Autor: D. Berstan, M. Y. Qureshi, G. Gordon Cameron, Malcolm D. Ingram, C. Rousselot
Rok vydání: 1998
Předmět:
Zdroj: Polymer International. 47:16-19
ISSN: 1097-0126
0959-8103
DOI: 10.1002/(sici)1097-0126(199809)47:1<16::aid-pi18>3.0.co;2-b
Popis: Ion-conducting gels containing poly(methyl methacrylate), propylene carbonate and lithium perchlorate have been studied by ESR spectroscopy using spin-probe and spin-label techniques. Trends in T 50G with increasing salt concentration observed with different polymer contents are indicative of strong cation-matrix interactions which may restrict cation mobility in these systems.
Databáze: OpenAIRE