Non-additive Effects of Structural Factors in Pyridine Catalyzed Reactions of Phenyloxirane with N-aroylbenzenesulfonamides

Autor:	I. V. Sadovaya, I. V. Shpan’ko
Rok vydání:	2020
Předmět:	chemistry.chemical_compound Reaction mechanism Chemistry Pyridine Cross correlation analysis General Chemistry Medicinal chemistry Catalysis
Zdroj:	Croatica chemica acta. 93:67-71
ISSN:	1334-417X 0011-1643
DOI:	10.5562/cca3658
Popis:	The combined influence of structural factors (Y, Z substituents) on the rate of catalyzed by Z-substituted pyridines reactions of phenyloxirane with Y-substituted N-aroylbenzenesulfonamides in acetonitrile at 293 K was studied. A cross-correlation analysis of the results of a multifactor kinetic experiment was carried out. A polylinear regression, that adequately describes the non-additive effects of substituents Y and Z, was calculated. Due to the interaction of the joint effects of structure, the cross-reaction series exhibits isoparametric properties. The mechanism of the catalytic process has been discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::776ccf902f0ad6024c4b946f81fdd206 https://doi.org/10.5562/cca3658 Zobrazit plný text záznamu Plný text ve formátu PDF